Titanium Oxide

Titanium Oxide


CAS No. 13463-67-7 | Chemical Formula TiO2

Molecular Weight 79.87 EC No. 236-675-5 MDL No. MFCD00011269

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Description

Description

Titanium dioxide, also known as titanium(IV) oxide or titania, when used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. It is sourced from ilmenite, rutile, and anatase.

The pigmentary form makes use of titanium dioxide’s excellent light-scattering properties in applications that require white opacity and brightness.

Chemical formula:TiO2

Molar mass:79.866 g/mol

Appearance:White solid

Odor  : Odorless

Density :4.23 g/cm3 (rutile) 3.78 g/cm3 (anatase)

Melting point:1.843 °C (3.349 °F; 2.116 K)

Boiling point:2.972 °C (5.382 °F; 3.245 K)

Solubility in water: Insoluble

Band gap:3.05 eV (rutile)

Specification

Specification

Rutile TiO2

Test ItemTest Result
TiO2 Content %≥94
Whiteness CIE L*a*b*197698.6
1.7
Tint reducing power≥1880
105 Volatile content %≤0.6
Water soluble matter %≤0.08
PH Value of aqueou suspension8.2
Oil absorption g/100g≤20
Residue on sieve 45μ(%)max %≤0.01
Specific resistance  Ω.m≥170
White degree (contrast to the standard sample)Similar
Dispersibility≥6.5
Scattering power (contrast to the standard sample) %≥97.8

Anatase TiO2

Test ItemTest Result
TiO2  %98.79
105℃ volatile %0.30
Whiteness95.78
Water soloble objects  %0.39
Residue(45um)%0.049
PH value of aqueou suspension8.06
Oil absorption , g/100g19.83
Hiding power104
Moisture0.4
Application

Application

1.    Paints and Coatings: Titanium dioxide provides opacity and durability, while helping to ensure the longevity of the paint and protection of the painted surface.

2.    Plastics, Adhesives and Rubber: Titanium dioxide can help minimize the brittleness, fading and cracking that can occur in plastics and other materials as a result of light exposure.

3.    Cosmetics: Pigment-grade titanium dioxide is use in some cosmetics to aid in hiding blemishes and brightening the skin. Titanium dioxide allows for the use of thinner coatings of make-up material for the same desired effect.

4.    Paper: Titanium dioxide is used to coat paper, making it whiter, brighter and more opaque.

5.    Food Contact Materials and Ingredients.

MSDS

MSDS

MATERIAL SAFETY DATA SHEETS

According to the UN GHS revision 8

Version: 1.0

Creation Date: Nov 20, 2020

Revision Date: Nov 20, 2020

SECTION 1: Identification


1.1

GHS Product identifier

Product name

Titanium Dioxide


1.2

Other means of identification

Product number

Other names

Titanium(IV) oxide,Aeroxide P25;Titanium(IV) oxide,anatase powder;Titanium dioxide,anatase


1.3

Recommended use of the chemical and restrictions on use

Identified uses

Industrial and scientific research uses.

Uses advised against

no data available


1.4

Supplier’s details

Company

Shanghai Greenearth Chemicals Co.,Ltd

Address

Building 2, No.5555, Shenzhuan Hwy, Shanghai , China

Telephone

+86-021-3776-2181

1.5Emergency phone number

Emergency phone number

+86-021-3776-2181

Service hours

Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

SECTION 2: Hazard identification


2.1

Classification of the substance or mixture

Not classified.


2.2

GHS label elements, including precautionary statements

Pictogram(s)No symbol.
Signal word

No signal word

Hazard statement(s)

none

Precautionary statement(s)
Prevention

none

Response

none

Storage

none

Disposal

none


2.3

Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients


3.1

Substances

Chemical nameCommon names and synonymsCAS numberEC number
Titanium DioxideTitanium dioxide13463-67-7236-675-5

SECTION 4: First-aid measures


4.1

Description of necessary first-aid measures

If inhaled

Fresh air, rest.

Following skin contact

Rinse and then wash skin with water and soap.

Following eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Following ingestion

Rinse mouth.


4.2

Most important symptoms/effects, acute and delayed

no data available


4.3

Indication of immediate medical attention and special treatment needed, if necessary

no data available

SECTION 5: Fire-fighting measures


5.1

Suitable extinguishing media

Use dry chemical, carbon dioxide or alcohol-resistant foam.


5.2

Specific hazards arising from the chemical

Not combustible.


5.3

Special protective actions for fire-fighters

In case of fire in the surroundings, use appropriate extinguishing media.

SECTION 6: Accidental release measures


6.1

Personal precautions, protective equipment and emergency procedures

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers.


6.2

Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.


6.3

Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

SECTION 7: Handling and storage


7.1

Precautions for safe handling

Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.


7.2

Conditions for safe storage, including any incompatibilities

Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

SECTION 8: Exposure controls/personal protection


8.1

Control parameters

Occupational Exposure limit values

TLV: 10 mg/m3, as TWA; A4 (not classifiable as a human carcinogen).MAK: 0.3 mg/m3; peak limitation category: II(8); carcinogen category: 4; pregnancy risk group: C

Biological limit values

no data available


8.2

Appropriate engineering controls

Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.

8.3Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear safety spectacles.

Skin protection

Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Use local exhaust or breathing protection.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state

COLOURLESS-TO-WHITE CRYSTALLINE POWDER.

Colour

no data available

Odour

no data available

Melting point/freezing point

1855°C

Boiling point or initial boiling point and boiling range

>135°C

Flammability

no data available

Lower and upper explosion limit/flammability limit

no data available

Flash point

27°C

Auto-ignition temperature

no data available

Decomposition temperature

no data available

pH

no data available

Kinematic viscosity

no data available

Solubility

no data available

Partition coefficient n-octanol/water

no data available

Vapour pressure

no data available

Density and/or relative density

4.26g/mLat 25°C(lit.)

Relative vapour density

no data available

Particle characteristics

no data available

SECTION 10: Stability and reactivity


10.1

Reactivity

no data available


10.2

Chemical stability

no data available


10.3

Possibility of hazardous reactions

no data available


10.4

Conditions to avoid

no data available


10.5

Incompatible materials

no data available


10.6

Hazardous decomposition products

no data available

SECTION 11: Toxicological information

Acute toxicity

  • Oral: no data available
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

A nuisance-causing concentration of airborne particles can be reached quickly when dispersed.

SECTION 12: Ecological information


12.1

Toxicity

  • Toxicity to fish: no data available
  • Toxicity to daphnia and other aquatic invertebrates: no data available
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available


12.2

Persistence and degradability

no data available


12.3

Bioaccumulative potential

no data available


12.4

Mobility in soil

no data available


12.5

Other adverse effects

no data available

SECTION 13: Disposal considerations


13.1

Disposal methods

Product

The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information


14.1

UN Number

ADR/RID: Not dangerous goods. (For reference only, please check.)IMDG: Not dangerous goods. (For reference only, please check.)IATA: Not dangerous goods. (For reference only, please check.)


14.2

UN Proper Shipping Name

ADR/RID: Not dangerous goods. (For reference only, please check.)IMDG: Not dangerous goods. (For reference only, please check.)IATA: Not dangerous goods. (For reference only, please check.)


14.3

Transport hazard class(es)

ADR/RID: Not dangerous goods. (For reference only, please check.)IMDG: Not dangerous goods. (For reference only, please check.)IATA: Not dangerous goods. (For reference only, please check.)


14.4

Packing group, if applicable

ADR/RID: Not dangerous goods. (For reference only, please check.)IMDG: Not dangerous goods. (For reference only, please check.)IATA: Not dangerous goods. (For reference only, please check.)


14.5

Environmental hazards

ADR/RID: NoIMDG: NoIATA: No


14.6

Special precautions for user

no data available


14.7

Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information


15.1

Safety, health and environmental regulations specific for the product in question

Chemical nameCommon names and synonymsCAS numberEC number
Titanium DioxideTitanium dioxide13463-67-7236-675-5
European Inventory of Existing Commercial Chemical Substances (EINECS)Listed.
EC InventoryListed.
United States Toxic Substances Control Act (TSCA) InventoryListed.
China Catalog of Hazardous chemicals 2015Not Listed.
New Zealand Inventory of Chemicals (NZIoC)Listed.
Philippines Inventory of Chemicals and Chemical Substances
(PICCS)
Listed.
Vietnam National Chemical InventoryListed.
Chinese Chemical Inventory of Existing Chemical Substances (China
IECSC)
Listed.
Korea Existing Chemicals List (KECL)Listed.

SECTION 16: Other information

Information on revision

Creation DateNov 20, 2020
Revision DateNov 20, 2020

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS – The International Chemical Safety Cards (ICSC), website:
    http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
    http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
    http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website:
    http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA – European Chemicals Agency, website: https://echa.europa.eu/
Any questions regarding this SDS, Please send your inquiry to [email protected]

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.

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